[η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV)
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چکیده
منابع مشابه
4-tert-Butylpyridinium triiodide–4-tert-butylpyridine (1/1)
The title compound, C(9)H(14)N(+)·I(3) (-)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl-pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I-I) and a bond angle of 177.55 (3)° (I-I-I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotato...
متن کامل1 , 8 - bis ( 2 - hydroxy - 3 , 5 - di - tert - butylbenzyl ) - 4 , 11 - dibenzyl - 1 , 4 , 8 , 11 - tetraazacyclotetradecane
A cyclam (1,4,8,11-tetraazacyclotetradecane)-based macrocycle bearing two benzyl and two 2-hydroxy-3,5-di-tert-butylbenzyl pendent arms was synthesized and characterized using spectroscopic techniques and single crystal X-ray diffraction. The macrocycle crystallizes in the triclinic space group P-1, with the asymmetric unit containing one-half of the molecule. The structure is stabilized by hyd...
متن کامل(±)-1-{8′-(tert-Butyldiphenylsilyloxymethyl)-1′,7′-dioxaspiro[5.5]undecan-2′-yl}uridine
The crystal structure of the title compound, C(30)H(38)N(2)O(5)Si, has been investigated to establish the relative stereochemistry at the spiro ring junction and the two anomeric centres. Each of the O atoms in the tetra-hydro-pyran rings adopts an axial position on the neighbouring ring. This bis--diaxial conformation is adopted, thus gaining maximum stablization from the anomeric effect. The ...
متن کاملBis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ2 N 1,N 8:N 8](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ2 N,N′)lithiumsodium
In the heterometallic title bulky amido complex, [LiNa(C15H21N2Si)2(C6H16N2)], both alkali metal ions are four-coordinated with distorted tetra-hedral geometries. The Li(+) ion is N,N'-chelated by the N-silylated amido ligand, with Li-N = 2.015 (5) and 2.074 (5) Å. The two amido ligands are arranged cis to each other. The mol-ecule exhibits a twofold rotational symmetry operation along the Li-N...
متن کامل1-(4-tert-Butylbenzyl)-2-(4-tert-butylphenyl)-1H-benzimidazole
In the mol-ecule of the title compound, C(28)H(32)N(2), the benzimidazole ring system is almost planar [maximum deviation = 0.0221 (15) Å] and forms dihedral angles of 85.86 (4) and 32.09 (6)° with the benzene rings. In the crystal structure, mol-ecules are linked into chains running parallel to the a axis by inter-molecular C-H⋯N hydrogen bonds. The methyl groups of a tert-butyl group are rota...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2006
ISSN: 1600-5368
DOI: 10.1107/s1600536806021726